After an engaging first leg finished 2-2 in Lisbon, the return was far more tight and the guests had done close to nothing to compromise before Nunez struck.
The Uruguayan beat Ajax goalkeeper Andre Onana to head in a whipped free-kick with 13 minutes to go.
Ajax ruled and Sebastien Haller had the ball in the net from the get-go, however Dusan Tadic was offside in the development.
The Benfica match-victor suggested by Suarez
However for all the house side's belonging they battled to separate an unfaltering Benfica guard that was well marshaled by veteran focus backs Nicolas Otamendi and previous Ajax and Spurs man Jan Vertonghen.
Belgian Vertonghen likewise headed wide from a unique opportunity for the guests, who showed little desire and looked probably going to compromise from a set-piece.
Furthermore, that was the way it ended up, with Nunez springing up with the unequivocal objective in the tie from Alex Grimaldo's brilliant conveyance.
Antony had looked energetic for the Dutch outfit and terminated on track from distance prior to heading one more exertion over the crossbar - as what had been a light climate inside the Johan Cruyff Arena started to turn cheeky.
In the end it was Benfica's vociferous voyaging support who were left reciting as their players delighted in festivals on the pitch, with the Portuguese outfit arriving at the last eight of the Champions League interestingly since the 2015-16 mission.
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