The Real Madrid player scored either side of Neymar and Philippe Coutinho punishments for the hosts, who had previously arrived at the finals in Qatar.
Everton forward Richarlison added a stoppage-time fourth for Brazil.
Uruguay and Ecuador likewise got programmed capability during the current year's competition on Thursday.
They will join bunch pioneers Brazil and second-set Argentina, who play Venezuela on Friday, at the current year's competition.
Uruguay beat Peru 1-0 while Ecuador lost 3-1 to Paraguay, however fifth-put Peru's loss implies they can't currently get both of them.
Peru, Colombia and Chile will presently seek fifth spot and a play-off spot against a group from the Asian confederation.
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