The team that has never lost a match against Real Madrid in the UEFA Champions League is Arsenal FC.
The two teams have faced each other six times in the Champions League, with Arsenal winning two and drawing four. In those six matches, Arsenal have kept a clean sheet against Real Madrid in four at home and two away, which leaves Real Madrid unable to score a single goal against Arsenal in the tournament.
The first time the two teams met in the Champions League was in the 2005-06 season, in the round of 16. Arsenal won the first leg 1-0 at Madrid's Santiago Bernabeu stadium thanks to a goal from Thierry Henry. The second leg at Highbury in London ended in a 0-0 draw, enough to send Arsenal into the quarter-finals thanks to the away goals rule.
The second time the two teams met was in the group stage of the 2006-07 season. The first match at the Emirates Stadium in London ended in a 0-0 draw, while the second match at the Santiago Bernabeu Stadium in Madrid also ended in a 0-0 draw.
The third time the two teams met was in the round of 16 for the 2007-08 season. Arsenal won the first leg 1-0 at the Emirates Stadium in London thanks to a goal from Cesc Fabregas. The second leg at Madrid's Santiago Bernabeu stadium ended in a 0-0 draw, enough to send Arsenal into the quarter-finals.
In the 2013–14 season, Arsenal and Real Madrid were placed in the same group. The first game at Emirates Stadium in London ended with a 1-0 victory for Arsenal thanks to a goal from Aaron Ramsey. The second game at Madrid's Santiago Bernabeu stadium ended in a 2-0 win for Real Madrid, with goals from Karim Benzema and Cristiano Ronaldo.
The most recent encounter between the two teams was in the group stage of the 2019-20 season. The opener at Madrid's Santiago Bernabeu stadium ended in a 2-2 draw, with goals from Gabriel Martinelli and Lucas Torreira for Arsenal. The second match at the Emirates Stadium in London also ended in a 2-2 draw, with goals from Pierre-Emerick Aubameyang and Hector Bellerin for Arsenal.
Overall, Arsenal's record against Real Madrid in the Champions League is 2 wins, 4 draws and no loss, with a total of 6 clean sheets.
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